By L. A. Tavadyan, G. A. Martoyan
English model of: Analiz kineticheskikh modelei khimicheskikh reak'tsionnykh sistem.
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Additional info for Analysis of Kinetic Models of Chemical Reaction Systems: Value Approach
11). Thus, the kinetic trajectories of sensitivities for concentration of reaction species (ci) may be determined by the rate constants of all the steps. For this, as we have made sure, the equation system needs to be solved with the number of equations equal to the number of individual steps n; where each of these equations, in turn, includes 2m differential equations. A number of other methods that facilitate the calculation of differential sensitivities is described in the literature. 11); the Green‟s function method [47,48]; the method of polynomial approximation developed by Hwang [49,50].
Let us consider one more important aspect. Simplification of the reaction mechanism by elimination of unimportant constituents is one of the methods for the reduction of its mathematical dimensionality [35-40]. In other words, it leads to the reduction of the number of differential (kinetic) equations to be integrated, underlying the reaction mathematical model. Thus, it facilitates computational procedures, as well as it analyses the kinetic model, in terms of both its use of predicting the reaction behavior under new conditions and for its control.
Martoyan kinetic models, due to the simplicity of calculations and the obviousness of the data obtained. We shall try to give additional arguments concerning this issue in subsequent sections. 2. Determination of the Base Mechanism for a Complex Chemical Reaction. Application of the Value Method for Reduction of Reaction Mechanisms Designing the appropriate kinetic scheme, which consists of a set of elementary transformations, is a main step to identify reaction mechanisms. In fact, this is the stage of setting up a hypothesis.